Kinetic Theory of Matter

🔹 Basic Postulates of Kinetic Theory

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  1. All matter is made of tiny particles
    • Particles are atoms or molecules
    • Extremely small and numerous
    • Cannot be seen with ordinary microscope
  2. Particles are in constant motion
    • Never completely at rest
    • Motion increases with temperature
    • Different types of motion in different states
  3. Particles attract each other
    • Forces are always attractive
    • Strength varies with distance
    • Determine physical properties
  4. Kinetic energy depends on temperature
    • Higher temperature = More kinetic energy
    • Kinetic energy opposes attractive forces
    • Balance determines state of matter

🔹 Kinetic Energy and Temperature

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  • Higher temperature → Higher kinetic energy → More particle motion
  • Lower temperature → Lower kinetic energy → Less particle motion
  • Absolute zero (-273°C) → Minimum possible kinetic energy
  • Heating: Increases particle motion, weakens attractive forces
  • Cooling: Decreases particle motion, strengthens attractive forces
  • State changes: Occur when kinetic energy overcomes or succumbs to attractive forces

🔹 Explaining Properties Using Kinetic Theory

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  • Increased kinetic energy pushes particles apart
  • Overcome attractive forces partially
  • Matter expands in all states
  • Random particle motion causes mixing
  • Faster at higher temperatures
  • Occurs in all states but most prominent in gases
  • Particles collide with container walls
  • More collisions = Higher pressure
  • Pressure increases with temperature and decreases with volume